CobaltMaghrebV1, France, Analysis, bibRecord, 000333

A New Nasicon-Type Phosphate Co0.5Ti2(PO4)3: I. Elaboration, Optical and Magnetic Properties

Identifieur interne : 000333 ( France/Analysis ); précédent : 000332; suivant : 000334

A New Nasicon-Type Phosphate Co0.5Ti2(PO4)3: I. Elaboration, Optical and Magnetic Properties

Auteurs : R. Olazcuaga [France] ; J. M Dance [France] ; G. Le Flem [France] ; J. Derouet [France] ; L. Beaury [France] ; P. Porcher [France] ; A. El Bouari [Maroc] ; A. El Jazouli [Maroc]

Source :

Journal of Solid State Chemistry [ 0022-4596 ] ; 1999.

RBID : ISTEX:7EA26E1087D5A09E41F4A2B3CD8F29121642B61B

Descripteurs français

Pascal (Inist)
- 6166F, 7530, 7630, Champ cristallin, Co O P Ti, Co0,5Ti2(PO4)3, Cobalt phosphate, Composé quaternaire, Etude expérimentale, Propriété magnétique, RPE, Spectre absorption, Structure cristalline, Titane phosphate.

English descriptors

KwdEn :
- Absorption spectra, Cobalt phosphates, Crystal field, Crystal structure, ESR, Experimental study, Magnetic properties, Quaternary compounds, Titanium phosphates.

Abstract

A new cobalt titanium monophosphate has been prepared by low temperature method. It crystallizes with the Nasicon-type structure. The indexation of the X-ray diffraction pattern is consistent with theR3or theR32 space groups. The atomic arrangement is a three-dimensional framework formed by PO4tetrahedra sharing corners with TiO6octahedra. Co2+is located in half of the antiprismM(1) sites in a centered (R3) or off- centered (R32) position. The optical, EPR and magnetic data can account for a pure ionic Co–O bond.

Url:

https://api.istex.fr/document/7EA26E1087D5A09E41F4A2B3CD8F29121642B61B/fulltext/pdf

DOI: 10.1006/jssc.1998.8097

Affiliations:

France, Maroc
Aquitaine, Nouvelle-Aquitaine, Île-de-France
Meudon, Pessac

Links to Exploration step

ISTEX:7EA26E1087D5A09E41F4A2B3CD8F29121642B61B

Le document en format XML

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A New Nasicon-Type Phosphate Co0.5Ti2(PO4)3: I. Elaboration, Optical and Magnetic Properties

A New Nasicon-Type Phosphate Co0.5Ti2(PO4)3: I. Elaboration, Optical and Magnetic Properties

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

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